山东省某典型工业区及周边不同土地利用类型土壤重金属污染特征及源解析

    Characteristics and source analysis of heavy metals pollution under different land use types in a typical industrial area and its surroundings in Shandong Province

    • 摘要: 明确土壤重金属污染状况及其来源是开展土壤污染风险管控的重要环节,以山东省某典型工业区作为研究案例,采用污染指数法、潜在生态危害指数法(potental ecological risk index, RI)对土壤中Hg、Cd、As、Pb、Cu、Cr、Zn和Ni污染状况进行了评价,并基于主成分分析(principal component analysis, PCA)使用绝对主成分-多元线性回归模型(absolute principal component analysis-multivariate linear regression, APCS-MLR)对重金属来源进行解析。结果表明: 土壤中Hg、Cu、Ni、Zn、As、Cr、Cd和Pb含量均值分别为0.05×10-6、26.7×10-6、19.0×10-6、64.0×10-6、6.5×10-6、54.2×10-6、0.17×10-6、29.5×10-6,其中Hg、Cd、Pb、Zn、Cu和As超过烟台市土壤背景值1.46、1.40、1.08、1.06、1.03和1.02倍; 不同土地利用类型土壤重金属含量均值从高到低为工业区>农业区>居民区,分别为313.7×10-6、177.2×10-6和175.2×10-6; 内梅罗污染指数均值为1.60,整体处于警戒—轻度污染水平,综合潜在生态危害指数值均值为125.1,整体属轻微危害水平,内梅罗污染指数和综合潜在生态危害指数均表明污染程度依次为工业区>农业区>居民区; APCS-MLR识别出金属冶炼工业源、土壤母质和农业混合源、大气沉降化石燃料燃烧源和污水灌溉为主导混合源4个污染源,贡献率分别为40.6%、33.6%、10.1%和15.8%。Cd、Zn、Cu、Cr和Pb主要来源于金属冶炼工业源,Ni和As主要来源于土壤母质和农业混合源,Hg主要来源于经由大气沉降化石燃料燃烧源。研究可为区域土壤重金属污染预防与治理提供基础依据。

       

      Abstract: Understanding the sources and status of heavy metals in soils is essential for effective risk management. In this study, a typical industrial area was taken as an example. The pollution status of Hg, Cd, As, Pb, Cu, Cr, Zn and Ni were assessed using the pollution index method and potential ecological risk index method. Based on PCA, the APCS-MLR model was used to analyze the pollution sources of heavy metals. Results indicated that the average concentrations of Hg, Cu, Ni, Zn, As, Cr, Cd, and Pb were 0.05×10-6, 26.7×10-6, 19.0×10-6, 64.0×10-6, 6.5×10-6, 54.2×10-6, 0.17×10-6, and 29.5×10-6, respectively, and Hg, Cd, Pb, Zn, Cu, and As exceeded background values of Yantai City by 1.46, 1.40, 1.08, 1.06, 1.03 and 1.02 times. The average concentrations of heavy metals in different land types were arranged in the order of industrial area>agricultural area>residential area, with values of 313.7×10-6, 177.2×10-6, and 175.2×10-6. The average Nemerow pollution index was 1.60, indicating an overall alert-slight pollution level, and the comprehensive potential ecological risk index was 125.1, representing a slight ecological risk. Both the Nemerow pollution index and comprehensive potential ecological risk index demonstrated that the pollution degree followed the order of industrial zone>agricultural zone>residential zone. APCS-MLR identified four pollution sources, that is metal smelting industry, mixed soil parent material and agricultural sources, atmospheric deposition fossil fuel combustion sources, and waste water irrigation dominant mixed sources, with the contribution rates of 40.6%, 33.6%, 10.1%, and 15.8%, respectively. Cd, Zn, Cu, Cr and Pb were mainly derived from metal smelting industry, Ni and As was primarily attributed to mixed soil parent material and agricultural sources, and Hg mainly originated from fossil fuel combustion sources via atmospheric deposition. This study could provide scientific basis for regional soil heavy metal pollution prevention and management.

       

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